jueves, 11 de septiembre de 2014

Carbon-13 NMR satellite

Carbon satellites are small peaks that can be seen shouldering the main peaks in an NMR spectrum. These peaks can occur in the NMR spectrum of any NMR active atom (e.g. 19F or 31P NMR) where those atoms adjoin a carbon atom (and where the spectrum is not 13C-decoupled, which is usually the case). However, Carbon satellites are most often encountered in proton NMR.
In the example of proton NMR, these peaks are not the result of proton-proton coupling, but result from the coupling of 1H atoms to an adjoining 13C atom. These small peaks are known as carbon satellites as they are small and appear around the main 1H peak i.e. satellite (around) to them. Carbon satellites are small because 13C only makes up about 1% of the atomic carbon content of carbon, the rest of the carbon atoms are predominantly NMR inactive 12C. Carbon satellites always appear as an evenly spaced pair around the main...

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